FEDERAL LABORATORIES -- SGA-400 FERRET BARRICADE PENETRATING 40MM CARTRIDGE MATERIAL SAFETY DATA SHEET NSN: 136500N060882 Manufacturer's CAGE: 21862 Part No. Indicator: A Part Number/Trade Name: SGA-400 FERRET BARRICADE PENETRATING 40MM CARTRIDGE =========================================================================== General Information =========================================================================== Company's Name: FEDERAL LABORATORIES Company's Street: ONE TUNNELTON RD Company's P. O. Box: 305 Company's City: SALTSBURG Company's State: PA Company's Country: US Company's Zip Code: 15681 Company's Emerg Ph #: 800-424-9300(CHEMTREC) Company's Info Ph #: 412-639-3511 Record No. For Safety Entry: 001 Tot Safety Entries This Stk#: 001 Status: SMJ Date MSDS Prepared: 13OCT94 Safety Data Review Date: 28JUN95 MSDS Preparer's Name: SCOTT MILLER Preparer's Company: SAME MSDS Serial Number: BXVYB =========================================================================== Ingredients/Identity Information =========================================================================== Proprietary: NO Ingredient: MALONONITRILE, O-CHLOROBENZYLIDENE-; (CS(O- CHLOROBENZYLMALONONITRILE)) Ingredient Sequence Number: 01 Percent: 3 NIOSH (RTECS) Number: OO3675000 CAS Number: 2698-41-1 OSHA PEL: 0.05 PPM (MFR) ACGIH TLV: 0.05 PPM (MFR) Other Recommended Limit: 2 MG/M3 (MFR) ------------------------------------- Proprietary: NO Ingredient: METHANE, DICHLORO-; (METHYLENE CHLORIDE) (SARA 313) (CERCLA) Ingredient Sequence Number: 02 Percent: 96 NIOSH (RTECS) Number: PA8050000 CAS Number: 75-09-2 OSHA PEL: 500 PPM ACGIH TLV: 50 PPM ------------------------------------- Proprietary: NO Ingredient: AMMONIUM,(9-(O-CARBOXYPHENYL)-6-(DIETHYLAMINO)-3H- XANTHEN-3- YLIDENE)DIETHYL-,CHLORIDE; (BASIC VIOLET 10 DYE) (SARA 313) Ingredient Sequence Number: 03 Percent: 1 NIOSH (RTECS) Number: BP3675000 CAS Number: 81-88-9 OSHA PEL: N/K (FP N) ACGIH TLV: N/K (FP N) ------------------------------------- Proprietary: NO Ingredient: SUPP DATA:CONFINED SPACE ENTRY. Ingredient Sequence Number: 04 NIOSH (RTECS) Number: 9999999ZZ OSHA PEL: NOT APPLICABLE ACGIH TLV: NOT APPLICABLE ------------------------------------- Proprietary: NO Ingredient: VENT:METHYLENE CHLORIDE MAY INDICATE AN AIR CONCENTRATION IN EXCESS OF 200 PPM. Ingredient Sequence Number: 05 NIOSH (RTECS) Number: 9999999ZZ OSHA PEL: NOT APPLICABLE ACGIH TLV: NOT APPLICABLE =========================================================================== Physical/Chemical Characteristics =========================================================================== Appearance And Odor: PLASTIC 40MM CARTRIDGE HOLDING ONE FERRET ROUND CNTNG RED/PURPLISH LIQ (SUPDAT) Boiling Point: 104F,40C Melting Point: 203F,95C Vapor Pressure (MM Hg/70 F): 390 @ STP Vapor Density (Air=1): N/A Specific Gravity: N/A Evaporation Rate And Ref: NOT APPLICABLE Solubility In Water: INSOLUBLE Percent Volatiles By Volume: N/A =========================================================================== Fire and Explosion Hazard Data =========================================================================== Flash Point: NOT APPLICABLE Lower Explosive Limit: N/A Upper Explosive Limit: N/A Extinguishing Media: WATER. Special Fire Fighting Proc: USE NIOSH/MSHA APPRVD PRESS DEMAND SCBA & FULL PROT EQUIP (FP N). SURROUND AREA SHOULD BE EVACUATED. USE EXTREME CAUT IN APPROACHING FIRES & DO SO FROM UPWIND. Unusual Fire And Expl Hazrds: THERMAL DECOMP PRODS MAY INCL HCL & PHOSGENE (FP N). WHEN HEATED TO DECOMP, IT EMITS TEAR GAS FUMES & TOX FUMES. CARTRIDGE CONTAINS 0.0375 OZS OF (SUPP DATA) =========================================================================== Reactivity Data =========================================================================== Stability: YES Cond To Avoid (Stability): OPEN FLAMES, HOT GLOWING SURFACES OR ELECTRIC ARCS. Materials To Avoid: CORROSIVE TO ALUMINUM & MAGNESIUM. Hazardous Decomp Products: HCL, PHOSGENE (FP N). CONTACT W/OPEN FLAME MAY CAUSE DECOMPOSITION PRODUCTS RELEASE. Hazardous Poly Occur: NO Conditions To Avoid (Poly): NOT RELEVANT =========================================================================== Health Hazard Data =========================================================================== LD50-LC50 Mixture: NONE SPECIFIED BY MANUFACTURER. Route Of Entry - Inhalation: YES Route Of Entry - Skin: YES Route Of Entry - Ingestion: YES Health Haz Acute And Chronic: ACUTE:MATL MAY BE IRRIT TO EYES, SKIN & RESP TRACT. OVEREXP MAY RSLT IN HDCH, DIZZ, LT HEAD & METAL FUME FEVER WHICH IS CHARACT BY CHILLS, FEVER, PROFUSE SWEATING, METALLIC TASTE, LABORED BRTHG, BLURRED VISION, BACK PAIN, NAUS & FATG. CHRONIC:MAY RSLT IN LUNG DMG. CHLOROCARBON MATLS HAVE PRDCD SENSIT (EFTS OF OVEREXP) Carcinogenicity - NTP: YES Carcinogenicity - IARC: YES Carcinogenicity - OSHA: NO Explanation Carcinogenicity: METHYLENE CHLORIDE:IARC MONOGRAPHS SUPP, VOL 7, PG 194, 1987:GRP 2B. NTP 7TH ANNUAL RPT ON CARCINS, 1994:ANTIC (SUPDAT) Signs/Symptoms Of Overexp: HLTH HAZ:OF MYOCARDIUM TO EPINEPHRINE IN LAB ANIMALS & COULD HAVE SIMILAR EFT IN HUMANS. ADRENOMIMETICS (E.G., EPINEPHRINE) MAY BE CONTRATINDICATED EXCEPT FOR LIFE-SUSTAINING USES IN HUMANS ACUTELY OR CHRONICALLY EXPOS TO CHLOROCARBONS (FP N). Med Cond Aggravated By Exp: ASTHMA, ANY RESPIRATORY CONDITION. Emergency/First Aid Proc: INHAL:REMOVE VICTIM TO FRESH AIR. MAINTAIN OPEN AIRWAY & RESTORE BRTHG IF NEC. SEEK MED ATTN IMMED. EYE:HOLD EYELIDS OPEN & FLUSH FOR AT LST 15 MINS W/COPIOUS AMTS OF WATER. SEEK MED ATTN IMMED. SKIN:REMOVE CONTAM CLTHG. WASH AREA W/SOAP & WATER. SEEK MED ATTN. INGEST:IF VICTIM IS CONSCIOUS, PROVIDE WATER & INDUCE VOMITING. SEEK MED ATTN IMMED. =========================================================================== Precautions for Safe Handling and Use =========================================================================== Steps If Matl Released/Spill: VENTILATE AREA. PROTECT AGAINST OVEREXPOSURE. DAMPEN MATERIAL W/WATER TO PREVENT DUST FORMATION. CAREFULLY SCOOP UP MATERIAL. PLACE INTO A CLOSED CONTAINER. Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER. Waste Disposal Method: DISPOSAL MUST BE I/A/W FEDERAL, STATE & LOCAL REGULATIONS (FP N). HAZARDOUS WASTE - F002 (SOLN IN PROJECTILE) & D001 (CARTRIDGE); DISP OF VIA LICENSED DISPOSAL FIRM. SEE EPA 40 CFR 261. Precautions-Handling/Storing: STORE IN A COOL, DRY, WELL-VENTILATED AREA AWAY FROM HEAT & DIRECT SUNLIGHT. PRLNG STOR/STOR AT LOW TEMPS WILL CAUSE COMPOSITION TO DECOMPOSE. Other Precautions: NO SMOKING IN AREA OF USE. DO NOT USE IN GENERAL VICINITY OF ARC WELDING, OPEN FLAMES OR HOT SURFACES. HEAT &/OR UV RADIATION MAY CAUSE THE FORMATION OF HCL &/OR PHOSGENE (FP N). =========================================================================== Control Measures =========================================================================== Respiratory Protection: USE NIOSH/MSHA APPRVD AIR SUPPLIED RESP FOLLOWING MFR'S REC WHENEVER AIR CONC OF >50 PPM IS EXPECTED. ACCORDING TO NIOSH, AIR PURIFYING RESPS SHOULD NOT BE USED W/METHYLENE CHLORIDE. USE NIOSH/MSHA APPRVD SUPPLIED AIR RESP IN POS (SUPDAT) Ventilation: LOC VENT IS PREF TO MEET PEL REQUIREMENTS. GEN VENT IS ACCEPT IF EXPOS IS MAINTAINED BELOW PEL. ODOR OF (ING 5) Protective Gloves: CHEM RESIST, VITON, PVA/EQUIV GLOVES. Eye Protection: ANSI APPROVED CHEM WORKERS GOGGS (FP N). Other Protective Equipment: WHEN HANDLING POWDERED MATL WEAR COVERALLS/ LONG SLEEVES. EYEWASH STATION & SAFETY SHOWER SHOULD BE AVAILABLE. Work Hygienic Practices: WASH THOROUGHLY AFTER HANDLING PRODUCT. Suppl. Safety & Health Data: APPEAR/ODOR:W/SHARP IRRIT ODOR. LOW CONCS OF CS SMELLS LIKE "PEPPER". EXPLO HAZ:SMOKELESS PWDR (NOT DETONATING EXPLO) TO EJECT FERRET PROJECTILE FROM CARTRIDGE CASING. EXPLAN OF CARCIN:TO BE PRESS MODE FOLLOWING ANSI Z117.7.1977 FOR TANK & (ING 4) =========================================================================== Transportation Data =========================================================================== =========================================================================== Disposal Data =========================================================================== =========================================================================== Label Data =========================================================================== Label Required: YES Technical Review Date: 28JUN95 Label Date: 19JUN95 Label Status: G Common Name: SGA-400 FERRET BARRICADE PENETRATING 40MM CARTRIDGE Chronic Hazard: YES Signal Word: DANGER! Acute Health Hazard-Moderate: X Contact Hazard-Moderate: X Fire Hazard-Severe: X Reactivity Hazard-Severe: X Special Hazard Precautions: ACUTE:INHALATION OF VAPORS MAY CONTRIBUTE TO THE OCCURRENCE OF IRREGULAR HEARTBEAT (FP N). MATERIAL MAY BE IRRITATING TO EYES, SKIN & RESPIRATORY TRACT. OVEREXPOSURE MAY RESULT IN HEADACHE, DIZZINESS, LIGHTHEADEDNESS & METAL FUME FEVER WHICH IS CHARACTERIZED BY CHILLS, FEVER, PROFUSE SWEATING, METALLIC TASTE, LABORED BREATHING, BLURRED VISION, BACK PAIN, NAUSEA & FATIGUE. CHRONIC:CANCER HAZARD. CONTAINS METHYLENE CHLORIDE WHICH IS LISTED AS A LIVER CARCINOGEN (FP N). MAY RESULT IN LUNG DAMAGE. Protect Eye: Y Protect Skin: Y Protect Respiratory: Y Label Name: FEDERAL LABORATORIES Label Street: ONE TUNNELTON RD Label P.O. Box: 305 Label City: SALTSBURG Label State: PA Label Zip Code: 15681 Label Country: US Label Emergency Number: 800-424-9300(CHEMTREC)